View information & documentation regarding Sodium azide, including CAS, MSDS & more. Avoid shock and friction. Accidents have occurred in these settings. Specific Hazards Arising from the Substance or Mixture. Registration dossier . Boston, MA: Butterworth-Heinemann Ltd., 1990. Sodium Azide must never be drain disposed, due to build-up of metal azides in metal plumbing lines and the toxicity to aquatic life. ... James O. Mutagenicity : No known significant effects or critical hazards. sodium azoimide . Proper personal protective equipment. Sodium azide is highly toxic. 5.2. H410-Very toxic to aquatic life with long lasting effects. Sodium Azide Solutions: Potential Hazards for Explosions from Improper Handling and Disposal, August 5, 2015. Hazards. Toxicological information Not available. Wear, “Azide Hazards with Automatic Blood Cell Counters,” Journal of Chemical Education, 52, A23-A25, January 1975. Sodium azide ≥99%; CAS Number: 26628-22-8; EC Number: 247-852-1; Linear Formula: N3Na; find Sigma-Aldrich-13412 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich. Chemical Safety: Sodium Azide Hazards January 11, 2010 | APPEARED IN VOLUME 88, ISSUE 2 ADVERTISEMENT. Sigma-Aldrich offers a number of Sodium azide products. Sodium Azide in Car Airbags Poses Growing Environmental Hazard, UA Scientist Says. N 2 O + 2 NaNH 2 → NaN 3 + NaOH + NH 3. CHEMICAL INFORMATION SHEET: SODIUM AZIDE, NaN3 SYNONYM(S) Azide, Azium, Sodium salt of hydrazoic acid CAS NUMBER 26628 -22 -8 MOLECULAR WEIGHT 65.02 PHYSICAL HAZARDS: * REACTIVE INCOMPATIBILITIES: When mixed with water or an acid, or comes in contact with a solid metal **it changes rapidly to form a toxic gas with a pungent odor. Sodium azide is a metabolic inhibitor that interferes with oxidative enzymes and inhibits phosphorylation. Conditions to Avoid Incompatible products. Sodium azide … Sodium azide 0.05 Yes 500 - 1,000 - SARA 304 RQ: 2,000,000 lbs / 908,000 kg SARA 313 Components: Sodium azide is subject to reporting requirements of Section 313, Title III of SARA. 5.3. Nitrogen-diluted bromine vapor passed over silver or sodium azide formed bromine azide, and often caused explosions /metal azides/. Avoid dust formation. Hazards and Safety. 26628-22-8 Revision Date 2007-07-01 Sodium azide exposure can result in headache, respiratory distress, and diarrhea. Warning: Ingestion of sodium azide (Na(N3)) may result in sudden onset of seizures or loss of consciousness. Incompatible Materials Acids, Oxidizing agents, Peroxides, Acid chlorides, Metals Hazardous Decomposition … Gives off irritating or toxic fumes (or gases) in a fire. Sodium azide is used as a chemical preservative in hospitals and laboratories. 302/304/311/312 extremely hazardous substances: Sodium azide SARA 313 toxic chemical notification and release reporting: Sodium azide CERCLA: Hazardous substances. A characteristic effect of acute administration of sodium azide to experimental animals is hypotension (Reinhardt and Britelli, 1982). Sodium azide tablets are stacked like small hockey pucks in two-inch-diameter metal canisters inside airbags. STOT - single exposure None known STOT - repeated exposure Central nervous system (CNS) Cardiovascular system Liver Kidney Heart spleen Aspiration hazard No information available Symptoms / effects,both acute and delayed No information available Sodium azide is currently undergoing testing for chronic oral toxicity in rats (NTP, 1985). US sodium azide 26628-22-8 REL NIOSH REL US sodium azide 26628-22-8 TLV® ACGIH® 2018 Notation STEL short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-minute period (unless otherwise specified) Safety Data Sheet acc. 100. Sodium azide is made industrially by the reaction of nitrous oxide, N 2 O with sodium amide in liquid ammonia as solvent:. Sodium azide, used mainly as a preservative in aqueous laboratory reagents and biologic fluids and as a fuel in automobile airbag gas generants, has caused deaths for decades. Its exposure potential for the general population increases as the use of airbags increase. TRANSPORT INFORMATION DOT UN/ID no. 65: No ingredient regulated by CA Prop 65 present. Plumbers can then accidentally detonate these compounds. Antibodies with 0.1% Sodium Azide Section 11. Great care must be taken to handle Sodium Azide in a manner that contamination with metals doesn’t occur, as the formation of metal azides can present an explosion hazard when formed crystals are left to dry. Sodium azide CAS-No. Sodium azide 26628-22-8 - - - - Chemical Name California Hazardous Waste Status Sodium azide 26628-22-8 Ignitable; Reactive 14. Sodium Azide Sodium Azide (IARC) IMIS: S113 Hydrazoic acid & Azide, Sodium trinitride, Smite, Azium, sodium salt NaN 3 carcinogenic classification: Group 3-not classifiable as to its carcinogenicity to humans CAS 26628-22-8 PUBCHEM N/A EC 247 … It is unlikely that a dilute sodium azide solution that … Many inorganic azides can be prepared directly or indirectly from sodium azide. ... sodium;azide . Trade names . Sodium Azide Handling. Risk of fire and explosion on contact with acids or metals. : Sodium azide Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). hazards should sodium azide come in contact with metals. Teratogenicity : No known significant effects or critical hazards. Sodium azide Synonyms & Trade Names Azide, Azium, Sodium salt of hydrazoic acid CAS No. to 29 CFR 1910.1200 App D 5% (w/v) Sodium Azide Version number: GHS 3.0 Avoid contact with acids or heavy metals. SARA 311/312 Hazards: N/A US State Regulations: California Prop. Sodium Azide (NaN 3) is an inorganic compound commonly used as the gas forming agent in airbag systems.It is both highly toxic and reactive. This material contains Sodium azide (CAS# 26628-22-8, 99+%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. 011-004 … If elapsed time since ingestion of sodium azide (Na(N3)) is unknown or suspected to be greater than 30 minutes, do not induce vomiting and proceed to Step 4. Handbook of Reactive Chemical Hazards 4th ed Bretherick, L. Handbook of Reactive Chemical Hazards. Sodium azide is very toxic to aquatic life and may cause long-term adverse effects in the aquatic environment. Physical hazards. 5. Lori Stiles. 26628-22-8 Revision Date 2007-07-01 Pennsylvania Right To Know Components Sodium azide CAS-No. However, sodium azide does have hazards. Sodium Azide Hazards and Disposal Sodium azide is used at UNO in the preservation of samples and stock solutions. Sodium azide (NaN3) | N3Na | CID 4427778 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. Hazard classification & labelling Hazard classification and labelling. A vehicle, upon sensing an impact, will send an electrical charge that heats the sodium azide to high temperatures – causing the rapid formation of nitrogen gas. Improper disposal down sink drains can cause Sodium Azide to react with Copper and Lead pipes to form highly explosive Lead Azide and Copper Azide. 6. 4th ed. Welcome to PubChem! Avoid disturbing corroded materials if the corrosion may be due to sodium azide. Additional Information. V. Daniels, S Ward, "A Rapid Test for the Detection of Substance which will Tarnish Silver" Studies in Conservation, 27(2), 1982, p.58-60. 1687 Proper shipping name SODIUM AZIDE Hazard Class 6.1 Packing Group II 15. Sodium azide Sodium azide Classification open all close all. Registration dossier . 26628-22-8 RTECS No. Preparation Inorganic azides. 26628-22-8 Revision Date 2007 -07 -01 SARA 311/312 Hazards Acute Health Hazard, Chronic Health Hazard Massachusetts Right To Know Components Sodium azide CAS-No. General : No known significant effects or critical hazards. 1687 Proper shipping name SODIUM AZIDE Hazard Class 6.1 Packing Group II IATA UN/ID no. Other identifiers . Special Protective Equipment for Firefighters Physical Hazards: Sodium azide can form explosive compounds when it comes into contact with or dries on metal surfaces, this includes metal spatulas or other metal lab equipment. Hydrazoic acid, sodium salt . LINK: International Chemical Safety Card for sodium azide. The driver-side airbag can is about 1 and 1/2 inches long and holds about 50 grams of sodium azide. Heavy-metal azides are notoriously explosive. Carcinogenicity : No known significant effects or critical hazards. Pennsylvania RTK: Sodium azide Massachusetts RTK: Sodium azide TSCA 8(b) inventory: Sodium azide SARA 302/304/311/312 extremely hazardous substances: Sodium azide SARA 313 toxic chemical notification and release reporting: Sodium azide CERCLA: Hazardous substances. H400-Very toxic to aquatic life. Sodium azide Revision Date 25-April-2019 Teratogenicity No information available. In order for sodium azide to form an explosive lead azide or copper azide it must come into contact with lead, copper and/or their lead/copper salts. Sodium azide Revision Date 25-Apr-2019 Reactive Hazard Yes Stability Risk of explosion by shock, friction, fire or other sources of ignition. Accidental mix of bleach and acid kills Buffalo Wild Wings employee; Sodium Azide. VY8050000: DOT ID & Guide 1687 153: Formula NaN 3: Conversion: IDLH N.D. See: IDLH INDEX : Exposure Limits NIOSH REL In fact, sodium azide is used in airbags for this very reason. Even dilute solutions of sodium azide must not be poured down the … Clean Air Act: This material does not contain any hazardous air pollutants. Sodium azide is a common preservative in many in vitro diagnostic products and is found in concentrations up to 0.1% in diluents used with automatic blood cell counters. Explosives Reason for no classification: ... hazard class not assessed Oxidising gases Reason for no classification: data conclusive but not sufficient for classification Gases under pressure In one case, sodium azide was poured into a drain, where it exploded and the toxic gas was inhaled (breathed in). Other Classifications: Hazard Statement. I.A.5. Sodium azide (NaN 3), a colorless-to-white crystalline solid that is odorless and moderately soluble in water, is the most prevalent inorganic compound used as an antibacterial and antimicrobial agent in bulk reagents and stock solutions in the in vitro diagnostics (IVD) industry.If you were to review the composition of almost any phosphate-buffered saline … It is often a better choice for this purpose than thimerosal, as sodium azide does not contain mercury. Ipecac should not be administered to children under 6 months of age. Registration dossier . SODIUM AZIDE: ICSC: 0950: Hydrazoic acid, sodium salt Azide Azium: April 2014: CAS #: 26628-22-8: UN #: 1687 EC Number: 247-852-1 ACUTE HAZARDS PREVENTION FIRE FIGHTING; FIRE & EXPLOSION: Combustible. This material does not contain any Class 1 … 1.0% de minimis concentration. Heat, flames and sparks. Most Popular in Safety.
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